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PMID: 19813703 Published · ppublish English Journal Article Research Support, N.I.H., Extramural

De novo design of antimicrobial polymers, foldamers, and small molecules: from discovery to practical applications.

Accounts of chemical research ·Vol. 43 ·No. 1 ·2010-01-19 ·Pages 30-9

Tew GN, Scott RW, Klein ML, Degrado WF

Abstract

Antimicrobial peptides (AMPs) provide protection against a variety of pathogenic bacteria and are, therefore, an important part of the innate immune system. Over the past decade, there has been considerable interest in developing AMPs as intravenously administered antibiotics. However, despite extensive efforts in the pharmaceutical and biotechnology industry, it has proven difficult to achieve this goal. While researchers have solved some relatively simple problems such as susceptibility to proteolysis, more severe problems have included the expense of the materials, toxicity, poor efficacy, and limited tissue distribution. In this Account, we describe our efforts to design and synthesize "foldamers"-- short sequence-specific oligomers based on arylamide and beta-amino acid backbones, which fold into well-defined secondary structures-- that could act as antimicrobial agents. We reasoned that small "foldamers" would be less expensive to produce than peptides, and might have better tissue distribution. It should be easier to fine-tune the structures and activities of these molecules to minimize toxicity. Because the activities of many AMPs depends primarily on their overall physicochemical properties rather than the fine details of their precise amino acid sequences, we have designed and synthesized very small "coarse-grained" molecules, which are far simpler than naturally produced AMPs. The molecular design of these foldamers epitomizes the positively charged amphiphilic structures believed to be responsible for the activity of AMPs. The designed oligomers show greater activity than the parent peptides. They have also provided leads for novel small molecule therapeutics that show excellent potency in animal models for multidrug resistant bacterial infections. In addition, such molecules can serve as relatively simple experimental systems for investigations aimed at understanding the mechanism of action for this class of antimicrobial agents. The foldamers' specificity for bacterial membranes relative to mammalian membranes appears to arise from differences in membrane composition and physical properties between these cell types. Furthermore, because experimental coarse-graining provided such outstanding results, we developed computational coarse-grained models to enable molecular dynamic simulations of these molecules with phospholipid membranes. These simulations allow investigation of larger systems for longer times than conventional molecular dynamics simulations, allowing us to investigate how physiologically relevant surface concentrations of AMP mimics affect the bilayer structure and properties. Finally, we apply the principles discovered through this work to the design of inexpensive antimicrobial polymers and materials.

MeSH Terms
Acrylamides/chemical synthesis,pharmacology Amino Acids/chemical synthesis,pharmacology Anti-Infective Agents/chemical synthesis,pharmacology Models, Molecular Molecular Conformation Polymers/chemical synthesis,pharmacology
Chemicals
Acrylamides Amino Acids Anti-Infective Agents Polymers
Authors & Affiliations
4 authors, click to expand affiliations / ORCID
Tew Gregory N
Department of Chemistry, University of Pennsylvania School of Medicine, Philadelphia, Pennsylvania 19104-6059, USA.
Scott Richard W
Klein Michael L
Degrado William F
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Article Info
Journal
Accounts of chemical research
Abbr.
Acc Chem Res
ISSN
1520-4898
Published
2010-01-19
Pages
30-9
Language
English
Region
United States
NLM ID
0157313
PMCID
PMC2808429
Subset
IM
Grants
NIGMS NIH HHS · R01 GM054616-05 · United States
NIGMS NIH HHS · R01 GM054616-08 · United States
NIGMS NIH HHS · GM54616 · United States
NIGMS NIH HHS · R01 GM054616-04 · United States
NIAID NIH HHS · AI74866 · United States
NIGMS NIH HHS · R01 GM054616-06 · United States
NIAID NIH HHS · R01 AI074866-01A1 · United States
NIGMS NIH HHS · R01 GM054616 · United States
NIGMS NIH HHS · R37 GM054616 · United States
NIAID NIH HHS · R01 AI074866 · United States
NIGMS NIH HHS · R01 GM054616-07 · United States
NIAID NIH HHS · R01 AI074866-02 · United States
NIAID NIH HHS · R56 AI074866 · United States
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