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PMID: 16411735 Published · ppublish English Journal Article Research Support, U.S. Gov't, Non-P.H.S. Review

The chain-length dependence test.

Accounts of chemical research ·Vol. 39 ·No. 1 ·2006-01-00 ·Pages 11-20

Stone MT, Heemstra JM, Moore JS

Abstract

Trends obtained from systematic studies based on chain-length variation have provided valuable insight and understanding into the behavior of m-phenylene ethynylene foldamers. The generalization of this experimental approach, the chain-length dependence test, is useful for studying solution conformation, packing in the solid state, specific intrachain interactions, and the contributions of end groups to a particular property.

MeSH Terms
Macrocyclic Compounds/chemical synthesis,chemistry Models, Molecular Molecular Conformation Molecular Structure Polymers/chemistry Structure-Activity Relationship Thermodynamics
Chemicals
Macrocyclic Compounds Polymers poly(phenylene ethynylene)
Authors & Affiliations
3 authors, click to expand affiliations / ORCID
Stone Matthew T
Department of Chemistry, 600 South Mathews Avenue, The University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA.
Heemstra Jennifer M
Moore Jeffrey S
Article Info
Journal
Accounts of chemical research
Abbr.
Acc Chem Res
ISSN
0001-4842
Published
2006-01-00
Pages
11-20
Language
English
Region
United States
NLM ID
0157313
Subset
IM
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